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Dzhemilev Reaction in Organic and Organometallic Synthesis
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Authors: Vladimir A.D'yakonov (Institute of PetroChemistry and Catalysis of Russian Academy of Sciences, Bashkortostan, Russian Federation) 
Book Description:
In the last 10−15 years the discovery of catalytic cycloalumination, cyclomagnesiation, and ethylmagnesiation reactions of olefins, dienes and allenes with the aid of alkyl and halogen alkyl Al and Mg derivatives under the action of Ti, Zr and Co complexes to obtain new classes of cyclic and acyclic organometallics namely aluminacyclopropanes, aluminacyclopropenes, aluminacyclopentanes, aluminacyclopent-2-enes, aluminacyclopenta-2,4-dienes, magnesacyclopentanes, magnesacyclopent-2-enes, and magnesacyclopenta-2,4-dienes are among the sound achievements in the field of organic and organometallic synthesis. These reactions are considered in the world scientific literature as Dzhemilev reactions. The monograph covers the data concerned the revealed first by Professor Dzhemilev phenomenon of catalytic replacement of transition metal atoms in metallacarbocycles by nontransition metal atoms to afford the said classes of organometallic compounds (OMC) and also the history of this discovery. Modern concepts and outlooks on mechanism of these reactions as well as the structure of the key intermediates responsible for the formation of target OMC are considered.

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Table of Contents:

Chapter 1. Introduction, pp. 1-2

Chapter 2. History of discovery, pp. 3-11

Chapter 3. Ethylmagnesiation of olefins catalyzed by Zr complexes, pp. 13-17

Chapter 4. Catalytic cycloalumination and cyclomagnesiation of olefins, acetylenes, and allenes mediated by Mg or Al alkyls, pp. 19-57

Chapter 5. On mechanism of olefin ethylmagnesiation and cycloalumination catalyzed by Zr complexes, pp. 59-68

Chapter 6. Synthesis of macro metallacarbocycles through the catalytic cyclometalation reaction of unsaturated compounds, pp. 69-73


      Chemistry Research and Applications
   Binding: Softcover
   Pub. Date: 2010
   Pages: 6x9
   ISBN: 978-1-60876-683-3
   Status: AV
Status Code Description
AN Announcing
FM Formatting
PP Page Proofs
FP Final Production
EP Editorial Production
PR At Prepress
AP At Press
AV Available
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Dzhemilev Reaction in Organic and Organometallic Synthesis