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Platinum and Uranium Hexafluorides: Structural Chemistry, NMR, Thermodynamic and Magnetic Properties, Effects of Spin-Orbit Interactions* $69.00
Authors: Svyatoslav P. Gabuda and Svetlana G. Kozlova (Nikolayev Institute of Inorganic Chemistry, Novosibirsk, Russia) 
Book Description:
This new book reviews research on the thermodynamic, magnetic susceptibility, solid-state 19F NMR and structural data for molecular hexafluorides and hexafluoro complexes related to interpretation of intermolecular interactions and structural properties. Along with conceptual problems associated with the application of methods theoretical and quantum chemistry, this work addresses the relationships between some fundamental properties of coordinate bonding and correlation effects, the electron-density transfer, and corrections for relativistic s-orbital contraction, d- and f-orbital expansion and destabilization and spin-orbit coupling.

Table of Contents:
1. Introduction

2. Thermodynamic Properties of Molecular Hexafluorides

3. Entropy of Polymorph Transitions in Hexafluorides

4. The Influence of Dn- Electrons on the Intermolecular Interactions in PtF6 and in hexafluorides of transition metals

5. X-Ray Data and Influence of Dn- Electrons on Intra- and Intermolecular Distances in PtF6 and WF6

6. Molecular Librations in Solid PtF6 and the 19F NMR Chemical Shielding Anisotropy

7. Interaction of the Oscillation Modes in Hexafluorides of D-Elements

8. Intermolecular interactions and the electron transfer to the Vacant s-, p-, and D-Orbitals of Central Ions in Hexafluorides

9. The Molecular Symmetry of MF2 and MF6 Molecules

10. The 19F NMR Chemical Shift Tensor in Solid UF6 and Related Compounds

11. Magnetic Properties of PtF6 and Isoelectronic Complexes KIrF6, K2OsF6 and K2RuF6

12. 19F NMR in PtF6 and Isoelectronic Complexes KIrF6, K2OsF6 , and K2RuF6

13. Small Symmetry Distortions in PtF6, other Hexafluoride Molecules and Isoelectronic Anions [MF6]- and [MF6]2-

14. Impact of Spin-Orbit Interactions in Hexafluorides and Hexafluorocomplexes

15. Relativistic Corrections in PtF6 and UF6

16. Conclusions

Index

   Series:
      Chemistry Research and Applications
   Binding: ebook
   Pub. Date: 2010
   Pages: 5.5 x 8.5
   ISBN: 978-1-61728-471-7
   Status: AV
  
Status Code Description
AN Announcing
FM Formatting
PP Page Proofs
FP Final Production
EP Editorial Production
PR At Prepress
AP At Press
AV Available
  
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Platinum and Uranium Hexafluorides: Structural Chemistry, NMR, Thermodynamic and Magnetic Properties, Effects of Spin-Orbit Interactions*