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Influence of the Solvents on Some Radical Reactions
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Editors: Gennady E. Zaikov ( Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, Moscow, Russia) Roman G. Makitra, Galina G. Midyana and Liliya I. Bazylyak ( Branch of Pisarzhevsky Institute of Physical Chemistry, National Academy of Scien
Book Description:
This book is based on results of a series of experimental investigations it was proved that the nature of medium has an essential influence both on the rate and the chemical mechanism of homolutical reactions. This influence can be quantitatively connected with the physical–chemical characteristics of medium based on the principle of linearity of free energies with the use of multiparametric equations.

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Table of Contents:
PREFACE:

CHAPTER I: COMPLICATIONS EXISTING AT CONSIDERATION OF FACTORS INFLUENCING ON KINETICS OF RADICAL REACTIONS, pp. 1-14

CHAPTER II: THE MEDIUM INFLUENCE ON THERMOLYSIS OF DIACYL– AND DIALKYLPEROXIDES, pp. 15-40

CHAPTER III:«DECOMPOSITION OF PERACIDS ESTERS», pp. 41-54

CHAPTER IV: DECOMPOSITION OF THE HYDROPEROXIDES AND REACTIONS
OF THE PHENOXY RADICALS, pp. 55-66

CHAPTER V: EFFECTS OF THE SOLVENTS IN THE OXIDATION REACTIONS», pp. 67-94
5.1. Oxidation of unsaturated cyclic hydrocarbons
5.2. Oxidation of saturated cyclic hydrocarbons
5.3. Oxidation of aldehydes

CHAPTER VI: THE MEDIUM INFLUENCE ON SOME OTHERS HOMOLYTIC REACTIONS, pp. 95-116
6.1. The medium influence on azobisisobutyronitrile (AIBN) decomposition
6.2. The medium influence on hydrocarbons halogenation
6.3. The examples of oxidation by peracetic acid

CONCLUSIONS pp.117-118

APPENDIX pp.119-124

INDEX pp.125-130

   Series:
      Chemistry Research and Applications
   Binding: Hardcover
   Pub. Date: 2011 - 1st Quarter
   Pages: pp.130
   ISBN: 978-1-60876-635-2
   Status: AV
  
Status Code Description
AN Announcing
FM Formatting
PP Page Proofs
FP Final Production
EP Editorial Production
PR At Prepress
AP At Press
AV Available
  
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Influence of the Solvents on Some Radical Reactions