Influence of fillers of different nature on properties of polymer compositions based on water solutions. pp.1009-1026
Authors: (L.m. Trufakina, Institute of Petrochemistry, Siberian Branch, Russian Academy of Sciences, Russia)
Abstract: At last few years more attention are attracted to the processes involving heterogeneous molecules and producing of polymer complexes. Investigations of macromoleculamacromolecula interactions are important both from scientific and practical point of view. The products of these reactions are intermolecular complexes possessing new properties different from properties of initial components. Intermolecular reactions are of interest for modeling processes in relatively simple polymer objects occur in complex biological systems and in their molecular and super-molecular formations. Of importance are peculiarities of synthesis macromolecules on polymer matrixes. During development of new polymer materials and compositions much attention is given to studying of possibilities for receiving of organized polymer complexes and developing in approaches to using physical – chemical methods for estimate on of states and properties. It is possible to receive compositions possessing specific properties owing to control of the conditions for making reactions between polymers or polymerizations. The mixtures of components various type are demanded selection temperature, concentrations initial components, their ratio and molecular mass, depths of passing reaction and so on. Reactivity of functional groups connected in chains can be differed from of the same groups in low molecular compounds. The nature of interactions between heterogeneous molecules in polymer complexes can be different: Van der Waals, electrostatic, hydrophobic interactions, hydrogen and co - ordinating bonds.