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Macroporous Materials: Controlled Synthesis, Characterization and Catalytic Properties pp. 1-30 $100.00
Authors:  (Changyan Li, Baocang Liu, Ying Jin, Jun Zhang, College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot, P. R. China, and others)
Abstract:
Porous materials can be divided into three types according to the aperture sizes. It is defined respectively as microporous materials when the aperture sizes are lower than 2 nm, mesoporous materials when the aperture sizes fall in range of 2-50 nm, and macroporous materials when the aperture sizes become larger than 50 nm. In some cases, microporous and mesoporous materials can result in an unacceptably slow diffusion rate of reactants considering their small aperture sizes, which hinders their practical application. In order to overcome this limitation, one promising method is to prepare macroporous materials with the aperture sizes in range of 50 nm-1.5 μm to increase the chemical diffusion rate. Thus, macroporous materials have attracted considerable interest due to their important applications in catalysis, and become a research hotspot in recent years. This paper is intended to review the recent advance in macroporous materials, especially three dimensionally ordered macroporous (3DOM) materials, and their catalytic application on the basis of the research achievement on 3DOM catalysts in the authors‘ group. The paper is composed of four sections: (1) Overview section — a concise overview on macroporous materials will be given; (2) Controlled Synthesis: — various kinds of synthesis techniques and principles will be introduced; (3) Characterization — A variety of characterization methods for the macroporous materials will be introduced; (4) Catalytic property — the catalytic property of macroporous materials will be reviewed. 


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Macroporous Materials: Controlled Synthesis, Characterization and Catalytic Properties pp. 1-30