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Sonochemistry in Water Organic Solutions
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Authors: Ants Tuulmets, Siim Salmar and Jaak Järv (University of Tartu, Tartu, Estonia) 
Book Description:
Sonochemistry and solution chemistry have been explicitly brought together by analyzing the effect of ultrasound on kinetics of ester hydrolysis and benzoin condensation, measured by the authors, and similar kinetic data for the solvolysis of tert-butyl chloride, compiled from literature. For the first time the power ultrasound, reaction kinetics and linear free-energy relationships were simultaneously exploited to study ionic reactions in water and aqueous-organic binary solvents and the importance of hydrophobic ground-state stabilization of reagents in aqueous solutions was discussed. This book presents and discusses this approach, which has opened novel perspectives for wider understanding of the effect of sonication on chemical reactions in solution, as well as on solvation phenomena in general.(Imprint: Novinka)

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Table of Contents:
1. INTRODUCTION pp.1-2

2. CURRENT VIEWS OF THE SONOCHEMISTRY IN SOLUTIONS pp.3-4

3. IONIC REACTIONS ACCELERATED BY ULTRASOUND pp.5-8

4. WATER AND HYDROPHOBIC INTERACTIONS pp.9-12

5. SONOCHEMICAL EFFECTS IN REACTION KINETICS pp.13-18

6. MODE OF ACTION OF ULTRASOUND ON REACTIONS IN SOLUTIONS pp.19-22

7. INFERENCES FROM SONICATION EFFECTS pp.23-26

8. SOME QUANTITATIVE CONSIDERATIONS pp.27-36

9. THE SOLVENT STRUCTURE AND SONICATION EFFECTS pp.37-40

10. THE DOMINO EFFECT IN UNDERSTANDING OF SOLVATION PHENOMENA pp.41-42

CONCLUSION pp.43-44

INDEX pp.51-54

   Series:
      Chemistry Research and Applications
   Binding: Hardcover
   Pub. Date: 2010
   Pages: pp.54
   ISBN: 978-1-61761-175-9
   Status: AV
  
Status Code Description
AN Announcing
FM Formatting
PP Page Proofs
FP Final Production
EP Editorial Production
PR At Prepress
AP At Press
AV Available
  
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Sonochemistry in Water Organic Solutions